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Aethan Velaryon was both master of ships and lord admiral to Kings Aegon I Targaryen and Aenys I Targaryen. His son, Daemon Velaryon, was also named to the post in the reigns of kings Maegor I and Jaehaerys I Targaryen
A Dance with Dragons
Daenerys Targaryen, Queen of Meereen, names the Pentoshi Captain Groleo as her lord admiral, but he has no ships as the Meereenese fleet sailed for Yunkai. Groleo is later executed while a hostage of the Yunkai'i.